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Fourier Transform Infrared Analysis (FTIR) provides a means of
characterizing a material’s chemical structure as well as
“fingerprinting” to confirm identity and condition.
The
technique is well-suited to organic based materials.
At
FORAY we use FTIR to test a wide range of materials -
plastic, polymeric coatings, adhesives, fabric dyes and foreign
contaminants in products.
We
use the practice of Attenuated Total Reflectance (ATR) to
examine specimens. Organic films on various substrates can be
quickly inspected with little need for sample preparation.
FTIR examples

Figure 1: Polymeric materials can be examined to determine
if they have undergone curing. The red spectrum is uncured
polyurethane coating compared to blue spectrum of cured polyurethane
coating. The uncured material shows the presence on the unreacted
isocyanate at 2273cm-1.
Micro IR Spectroscopy of a dyed polyester fibre (below)
separated from polyester cotton green fabric. Nodule like structures
were identified on the fibre and studied for potential dye
accumulation.

Figure 2: Microscopic image

Figure 3: IR spectroscopy of
nodule (blue) and adjacent normal area (red) on polyester fibre.
Note spectral differences in the region 1600-1750 cm-1;
1200-1300 cm-1.
Investigation of a foreign matter (white specks) in a reduced
spread/ butter sample. Using identification by FTIR combined with
elemental analysis and various other tests, it was concluded that
white speck in butter was nitrogen containing compound, possibly, a
protein.

Figure 4: Infrared analysis of the ‘white specks’ (red) and
control (black) samples. Note differences in the frequency region of
1000 cm-1 and 1500-1800 cm-1. The peaks at
1625 cm-1 and 1529 cm-1 are indicative of
presence of amide functional groups arising from protein type of
foreign material.
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